Conditions for the existence of the atmosphere. Formation of the atmosphere. Primary and secondary atmosphere. Formation and evolution of oxygen

The thickness of the atmosphere is approximately 120 km from the Earth's surface. The total mass of air in the atmosphere is (5.1-5.3) 10 18 kg. Of these, the mass of dry air is 5.1352 ±0.0003 10 18 kg, the total mass of water vapor is on average 1.27 10 16 kg.

Tropopause

The transition layer from the troposphere to the stratosphere, a layer of the atmosphere in which the decrease in temperature with height stops.

Stratosphere

A layer of the atmosphere located at an altitude of 11 to 50 km. Characterized by a slight change in temperature in the 11-25 km layer (lower layer of the stratosphere) and an increase in temperature in the 25-40 km layer from −56.5 to 0.8 ° (upper layer of the stratosphere or inversion region). Having reached a value of about 273 K (almost 0 °C) at an altitude of about 40 km, the temperature remains constant up to an altitude of about 55 km. This region of constant temperature is called the stratopause and is the boundary between the stratosphere and mesosphere.

Stratopause

The boundary layer of the atmosphere between the stratosphere and mesosphere. In the vertical temperature distribution there is a maximum (about 0 °C).

Mesosphere

Earth's atmosphere

Boundary of the Earth's atmosphere

Thermosphere

The upper limit is about 800 km. The temperature rises to altitudes of 200-300 km, where it reaches values ​​of the order of 1500 K, after which it remains almost constant to high altitudes. Under the influence of ultraviolet and x-ray solar radiation and cosmic radiation, ionization of the air (“ auroras”) occurs - the main regions of the ionosphere lie inside the thermosphere. At altitudes above 300 km, atomic oxygen predominates. The upper limit of the thermosphere is largely determined by the current activity of the Sun. During periods of low activity - for example, in 2008-2009 - there is a noticeable decrease in the size of this layer.

Thermopause

The region of the atmosphere adjacent to the thermosphere. In this region, the absorption of solar radiation is negligible and the temperature does not actually change with altitude.

Exosphere (scattering sphere)

Up to an altitude of 100 km, the atmosphere is a homogeneous, well-mixed mixture of gases. In higher layers, the distribution of gases by height depends on their molecular weights; the concentration of heavier gases decreases faster with distance from the Earth's surface. Due to the decrease in gas density, the temperature drops from 0 °C in the stratosphere to −110 °C in the mesosphere. However, the kinetic energy of individual particles at altitudes of 200-250 km corresponds to a temperature of ~150 °C. Above 200 km, significant fluctuations in temperature and gas density in time and space are observed.

At an altitude of about 2000-3500 km, the exosphere gradually turns into the so-called near space vacuum, which is filled with highly rarefied particles of interplanetary gas, mainly hydrogen atoms. But this gas represents only part of the interplanetary matter. The other part consists of dust particles of cometary and meteoric origin. In addition to extremely rarefied dust particles, electromagnetic and corpuscular radiation of solar and galactic origin penetrates into this space.

The troposphere accounts for about 80% of the mass of the atmosphere, the stratosphere - about 20%; the mass of the mesosphere is no more than 0.3%, the thermosphere is less than 0.05% of the total mass of the atmosphere. Based on the electrical properties in the atmosphere, the neutronosphere and ionosphere are distinguished. It is currently believed that the atmosphere extends to an altitude of 2000-3000 km.

Depending on the composition of the gas in the atmosphere, they emit homosphere And heterosphere. Heterosphere- This is the area where gravity affects the separation of gases, since their mixing at such an altitude is negligible. This implies a variable composition of the heterosphere. Below it lies a well-mixed, homogeneous part of the atmosphere, called the homosphere. The boundary between these layers is called the turbopause, it lies at an altitude of about 120 km.

Physiological and other properties of the atmosphere

Already at an altitude of 5 km above sea level, an untrained person begins to experience oxygen starvation and without adaptation, a person’s performance is significantly reduced. The physiological zone of the atmosphere ends here. Human breathing becomes impossible at an altitude of 9 km, although up to approximately 115 km the atmosphere contains oxygen.

The atmosphere supplies us with the oxygen necessary for breathing. However, due to the drop in the total pressure of the atmosphere, as you rise to altitude, the partial pressure of oxygen decreases accordingly.

In rarefied layers of air, sound propagation is impossible. Up to altitudes of 60-90 km, it is still possible to use air resistance and lift for controlled aerodynamic flight. But starting from altitudes of 100-130 km, the concepts of the M number and the sound barrier, familiar to every pilot, lose their meaning: there passes the conventional Karman line, beyond which the region of purely ballistic flight begins, which can only be controlled using reactive forces.

At altitudes above 100 km, the atmosphere is deprived of another remarkable property - the ability to absorb, conduct and transmit thermal energy by convection (i.e. by mixing air). This means that various elements of equipment on the orbital space station will not be able to be cooled from the outside in the same way as is usually done on an airplane - with the help of air jets and air radiators. At this altitude, as in space generally, the only way to transfer heat is thermal radiation.

History of atmospheric formation

According to the most common theory, the Earth's atmosphere has had three different compositions over time. Initially, it consisted of light gases (hydrogen and helium) captured from interplanetary space. This is the so-called primary atmosphere(about four billion years ago). At the next stage, active volcanic activity led to the saturation of the atmosphere with gases other than hydrogen (carbon dioxide, ammonia, water vapor). This is how it was formed secondary atmosphere(about three billion years before the present day). This atmosphere was restorative. Further, the process of atmosphere formation was determined by the following factors:

• leakage of light gases (hydrogen and helium) into interplanetary space;
• chemical reactions occurring in the atmosphere under the influence of ultraviolet radiation, lightning discharges and some other factors.

Gradually these factors led to the formation tertiary atmosphere, characterized by a much lower content of hydrogen and a much higher content of nitrogen and carbon dioxide (formed as a result of chemical reactions from ammonia and hydrocarbons).

Nitrogen

The formation of a large amount of nitrogen N2 is due to the oxidation of the ammonia-hydrogen atmosphere by molecular oxygen O2, which began to come from the surface of the planet as a result of photosynthesis, starting 3 billion years ago. Nitrogen N2 is also released into the atmosphere as a result of denitrification of nitrates and other nitrogen-containing compounds. Nitrogen is oxidized by ozone to NO in the upper atmosphere.

Nitrogen N 2 reacts only under specific conditions (for example, during a lightning discharge). The oxidation of molecular nitrogen by ozone during electrical discharges is used in small quantities in the industrial production of nitrogen fertilizers. Cyanobacteria (blue-green algae) and nodule bacteria that form rhizobial symbiosis with leguminous plants, the so-called, can oxidize it with low energy consumption and convert it into a biologically active form. green manure.

Oxygen

The composition of the atmosphere began to change radically with the appearance of living organisms on Earth, as a result of photosynthesis, accompanied by the release of oxygen and the absorption of carbon dioxide. Initially, oxygen was spent on the oxidation of reduced compounds - ammonia, hydrocarbons, ferrous form of iron contained in the oceans, etc. At the end of this stage, the oxygen content in the atmosphere began to increase. Gradually, a modern atmosphere with oxidizing properties formed. Since this caused serious and abrupt changes in many processes occurring in the atmosphere, lithosphere and biosphere, this event was called the Oxygen Catastrophe.

Noble gases

Air pollution

Recently, humans have begun to influence the evolution of the atmosphere. The result of his activities was a constant significant increase in the content of carbon dioxide in the atmosphere due to the combustion of hydrocarbon fuels accumulated in previous geological eras. Huge amounts of CO 2 are consumed during photosynthesis and absorbed by the world's oceans. This gas enters the atmosphere due to the decomposition of carbonate rocks and organic substances of plant and animal origin, as well as due to volcanism and human industrial activity. Over the past 100 years, the content of CO 2 in the atmosphere has increased by 10%, with the bulk (360 billion tons) coming from fuel combustion. If the growth rate of fuel combustion continues, then in the next 200-300 years the amount of CO 2 in the atmosphere will double and could lead to global climate change.

Fuel combustion is the main source of polluting gases (CO, SO2). Sulfur dioxide is oxidized by atmospheric oxygen to SO 3 in the upper layers of the atmosphere, which in turn interacts with water and ammonia vapor, and the resulting sulfuric acid (H 2 SO 4) and ammonium sulfate ((NH 4) 2 SO 4) are returned to the surface of the Earth in the form of the so-called. acid rain. The use of internal combustion engines leads to significant atmospheric pollution with nitrogen oxides, hydrocarbons and lead compounds (tetraethyl lead Pb(CH 3 CH 2) 4)).

Aerosol pollution of the atmosphere is caused by both natural causes (volcanic eruptions, dust storms, entrainment of drops of sea water and plant pollen, etc.) and human economic activities (mining ores and building materials, burning fuel, making cement, etc.). Intense large-scale release of particulate matter into the atmosphere is one of the possible causes of climate change on the planet.

see also

• Jacchia (atmosphere model)

Notes

Links

Literature

1. V. V. Parin, F. P. Kosmolinsky, B. A. Dushkov“Space biology and medicine” (2nd edition, revised and expanded), M.: “Prosveshcheniye”, 1975, 223 pp.
2. N. V. Gusakova“Environmental Chemistry”, Rostov-on-Don: Phoenix, 2004, 192 with ISBN 5-222-05386-5
3. Sokolov V. A. Geochemistry of natural gases, M., 1971;
4. McEwen M., Phillips L. Atmospheric Chemistry, M., 1978;
5. Wark K., Warner S. Air pollution. Sources and control, trans. from English, M.. 1980;
6. Monitoring of background pollution of natural environments. V. 1, L., 1982.

Earth
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At sea level 1013.25 hPa (about 760 mmHg). The global average air temperature at the Earth's surface is 15°C, with temperatures varying from approximately 57°C in subtropical deserts to -89°C in Antarctica. Air density and pressure decrease with height according to a law close to exponential.

The structure of the atmosphere. Vertically, the atmosphere has a layered structure, determined mainly by the features of the vertical temperature distribution (figure), which depends on the geographical location, season, time of day, and so on. The lower layer of the atmosphere - the troposphere - is characterized by a drop in temperature with height (by about 6°C per 1 km), its height from 8-10 km in polar latitudes to 16-18 km in the tropics. Due to the rapid decrease in air density with height, about 80% of the total mass of the atmosphere is located in the troposphere. Above the troposphere is the stratosphere, a layer generally characterized by an increase in temperature with height. The transition layer between the troposphere and stratosphere is called the tropopause. In the lower stratosphere, down to a level of about 20 km, the temperature changes little with height (the so-called isothermal region) and often even decreases slightly. Above that, the temperature increases due to the absorption of UV radiation from the Sun by ozone, slowly at first, and faster from a level of 34-36 km. The upper boundary of the stratosphere - the stratopause - is located at an altitude of 50-55 km, corresponding to the maximum temperature (260-270 K). The layer of the atmosphere located at an altitude of 55-85 km, where the temperature again drops with height, is called the mesosphere; at its upper boundary - the mesopause - the temperature reaches 150-160 K in summer, and 200-230 K in winter. Above the mesopause, the thermosphere begins - a layer characterized by a rapid increase in temperature, reaching 800-1200 K at an altitude of 250 km. In the thermosphere, corpuscular and X-ray radiation from the Sun is absorbed, meteors are slowed down and burned, so it acts as a protective layer of the Earth. Even higher is the exosphere, from where atmospheric gases are dispersed into outer space due to dissipation and where a gradual transition from the atmosphere to interplanetary space occurs.

Atmospheric composition. Up to an altitude of about 100 km, the atmosphere is almost homogeneous in chemical composition and the average molecular weight of the air (about 29) is constant. Near the Earth's surface, the atmosphere consists of nitrogen (about 78.1% by volume) and oxygen (about 20.9%), and also contains small amounts of argon, carbon dioxide (carbon dioxide), neon and other permanent and variable components (see Air ).

In addition, the atmosphere contains small amounts of ozone, nitrogen oxides, ammonia, radon, etc. The relative content of the main components of air is constant over time and uniform in different geographical areas. The content of water vapor and ozone is variable in space and time; Despite their low content, their role in atmospheric processes is very significant.

Above 100-110 km, dissociation of molecules of oxygen, carbon dioxide and water vapor occurs, so the molecular mass of air decreases. At an altitude of about 1000 km, light gases - helium and hydrogen - begin to predominate, and even higher the Earth's atmosphere gradually turns into interplanetary gas.

The most important variable component of the atmosphere is water vapor, which enters the atmosphere through evaporation from the surface of water and moist soil, as well as through transpiration by plants. The relative content of water vapor varies at the earth's surface from 2.6% in the tropics to 0.2% in polar latitudes. It falls quickly with height, decreasing by half already at an altitude of 1.5-2 km. The vertical column of the atmosphere at temperate latitudes contains about 1.7 cm of “precipitated water layer”. When water vapor condenses, clouds form, from which atmospheric precipitation falls in the form of rain, hail, and snow.

An important component of atmospheric air is ozone, concentrated 90% in the stratosphere (between 10 and 50 km), about 10% of it is in the troposphere. Ozone provides absorption of hard UV radiation (with a wavelength of less than 290 nm), and this is its protective role for the biosphere. The values ​​of the total ozone content vary depending on the latitude and season in the range from 0.22 to 0.45 cm (the thickness of the ozone layer at pressure p = 1 atm and temperature T = 0°C). In ozone holes observed in the spring in Antarctica since the early 1980s, ozone content can drop to 0.07 cm. It increases from the equator to the poles and has an annual cycle with a maximum in spring and a minimum in autumn, and the amplitude of the annual cycle is small in the tropics and grows towards high latitudes. A significant variable component of the atmosphere is carbon dioxide, the content of which in the atmosphere has increased by 35% over the past 200 years, which is mainly explained by the anthropogenic factor. Its latitudinal and seasonal variability is observed, associated with plant photosynthesis and solubility in sea water (according to Henry’s law, the solubility of a gas in water decreases with increasing temperature).

An important role in shaping the planet's climate is played by atmospheric aerosol - solid and liquid particles suspended in the air ranging in size from several nm to tens of microns. There are aerosols of natural and anthropogenic origin. Aerosol is formed in the process of gas-phase reactions from the products of plant life and human economic activity, volcanic eruptions, as a result of dust rising by the wind from the surface of the planet, especially from its desert regions, and is also formed from cosmic dust falling into the upper layers of the atmosphere. Most of the aerosol is concentrated in the troposphere; aerosol from volcanic eruptions forms the so-called Junge layer at an altitude of about 20 km. The largest amount of anthropogenic aerosol enters the atmosphere as a result of the operation of vehicles and thermal power plants, chemical production, fuel combustion, etc. Therefore, in some areas the composition of the atmosphere is noticeably different from ordinary air, which required the creation of a special service for observing and monitoring the level of atmospheric air pollution.

Evolution of the atmosphere. The modern atmosphere is apparently of secondary origin: it was formed from gases released by the solid shell of the Earth after the formation of the planet was completed about 4.5 billion years ago. During the geological history of the Earth, the atmosphere has undergone significant changes in its composition under the influence of a number of factors: dissipation (volatilization) of gases, mainly lighter ones, into outer space; release of gases from the lithosphere as a result of volcanic activity; chemical reactions between the components of the atmosphere and the rocks that make up the earth’s crust; photochemical reactions in the atmosphere itself under the influence of solar UV radiation; accretion (capture) of matter from the interplanetary medium (for example, meteoric matter). The development of the atmosphere is closely related to geological and geochemical processes, and over the last 3-4 billion years also to the activity of the biosphere. A significant part of the gases that make up the modern atmosphere (nitrogen, carbon dioxide, water vapor) arose during volcanic activity and intrusion, which carried them from the depths of the Earth. Oxygen appeared in appreciable quantities about 2 billion years ago as a result of photosynthetic organisms that originally arose in the surface waters of the ocean.

Based on data on the chemical composition of carbonate deposits, estimates of the amount of carbon dioxide and oxygen in the atmosphere of the geological past were obtained. Throughout the Phanerozoic (the last 570 million years of Earth's history), the amount of carbon dioxide in the atmosphere varied widely depending on the level of volcanic activity, ocean temperature and the rate of photosynthesis. For most of this time, the concentration of carbon dioxide in the atmosphere was significantly higher than today (up to 10 times). The amount of oxygen in the Phanerozoic atmosphere changed significantly, with a prevailing trend towards its increase. In the Precambrian atmosphere, the mass of carbon dioxide was, as a rule, greater, and the mass of oxygen was smaller compared to the Phanerozoic atmosphere. Fluctuations in the amount of carbon dioxide had a significant impact on the climate in the past, increasing the greenhouse effect with increasing concentrations of carbon dioxide, making the climate much warmer throughout the main part of the Phanerozoic compared to the modern era.

Atmosphere and life. Without an atmosphere, the Earth would be a dead planet. Organic life occurs in close interaction with the atmosphere and the associated climate and weather. Insignificant in mass compared to the planet as a whole (about a part in a million), the atmosphere is an indispensable condition for all forms of life. The most important of the atmospheric gases for the life of organisms are oxygen, nitrogen, water vapor, carbon dioxide, and ozone. When carbon dioxide is absorbed by photosynthetic plants, organic matter is created, which is used as a source of energy by the vast majority of living beings, including humans. Oxygen is necessary for the existence of aerobic organisms, for which the flow of energy is provided by oxidation reactions of organic matter. Nitrogen, assimilated by some microorganisms (nitrogen fixers), is necessary for the mineral nutrition of plants. Ozone, which absorbs hard UV radiation from the Sun, significantly weakens this part of solar radiation harmful to life. The condensation of water vapor in the atmosphere, the formation of clouds and subsequent precipitation supply water to land, without which no form of life is possible. The vital activity of organisms in the hydrosphere is largely determined by the amount and chemical composition of atmospheric gases dissolved in water. Since the chemical composition of the atmosphere significantly depends on the activities of organisms, the biosphere and atmosphere can be considered as part of a single system, the maintenance and evolution of which (see Biogeochemical cycles) was of great importance for changing the composition of the atmosphere throughout the history of the Earth as a planet.

Radiation, heat and water balances of the atmosphere. Solar radiation is practically the only source of energy for all physical processes in the atmosphere. The main feature of the radiation regime of the atmosphere is the so-called greenhouse effect: the atmosphere transmits solar radiation to the earth's surface quite well, but actively absorbs thermal long-wave radiation from the earth's surface, part of which returns to the surface in the form of counter radiation, compensating for radiative heat loss from the earth's surface (see Atmospheric radiation ). In the absence of an atmosphere, the average temperature of the earth's surface would be -18°C, but in reality it is 15°C. Incoming solar radiation is partially (about 20%) absorbed into the atmosphere (mainly by water vapor, water droplets, carbon dioxide, ozone and aerosols), and is also scattered (about 7%) by aerosol particles and density fluctuations (Rayleigh scattering). The total radiation reaching the earth's surface is partially (about 23%) reflected from it. The reflectance coefficient is determined by the reflectivity of the underlying surface, the so-called albedo. On average, the Earth's albedo for the integral flux of solar radiation is close to 30%. It varies from a few percent (dry soil and black soil) to 70-90% for freshly fallen snow. Radiative heat exchange between the earth's surface and the atmosphere significantly depends on albedo and is determined by the effective radiation of the earth's surface and the counter-radiation of the atmosphere absorbed by it. The algebraic sum of radiation fluxes entering the earth's atmosphere from outer space and leaving it back is called the radiation balance.

Transformations of solar radiation after its absorption by the atmosphere and the earth's surface determine the heat balance of the Earth as a planet. The main source of heat for the atmosphere is the earth's surface; heat from it is transferred not only in the form of long-wave radiation, but also by convection, and is also released during condensation of water vapor. The shares of these heat inflows are on average 20%, 7% and 23%, respectively. About 20% of heat is also added here due to the absorption of direct solar radiation. The flux of solar radiation per unit time through a single area perpendicular to the sun's rays and located outside the atmosphere at an average distance from the Earth to the Sun (the so-called solar constant) is equal to 1367 W/m2, changes are 1-2 W/m2 depending on cycle of solar activity. With a planetary albedo of about 30%, the time-average global influx of solar energy to the planet is 239 W/m2. Since the Earth as a planet emits on average the same amount of energy into space, then, according to the Stefan-Boltzmann law, the effective temperature of the outgoing thermal long-wave radiation is 255 K (-18 ° C). At the same time, the average temperature of the earth's surface is 15°C. The difference of 33°C is due to the greenhouse effect.

The water balance of the atmosphere generally corresponds to the equality of the amount of moisture evaporated from the Earth's surface and the amount of precipitation falling on the Earth's surface. The atmosphere over the oceans receives more moisture from evaporation processes than over land, and loses 90% in the form of precipitation. Excess water vapor over the oceans is transported to the continents by air currents. The amount of water vapor transferred into the atmosphere from the oceans to the continents is equal to the volume of the rivers flowing into the oceans.

Air movement. The Earth is spherical, so much less solar radiation reaches its high latitudes than the tropics. As a result, large temperature contrasts arise between latitudes. The temperature distribution is also significantly affected by the relative positions of the oceans and continents. Due to the large mass of ocean waters and the high heat capacity of water, seasonal fluctuations in ocean surface temperature are much less than on land. In this regard, in the middle and high latitudes, the air temperature over the oceans in summer is noticeably lower than over the continents, and higher in winter.

Uneven heating of the atmosphere in different regions of the globe causes a spatially inhomogeneous distribution of atmospheric pressure. At sea level, the pressure distribution is characterized by relatively low values ​​near the equator, increases in the subtropics (high pressure belts) and decreases in the middle and high latitudes. At the same time, over the continents of extratropical latitudes, the pressure is usually increased in winter and decreased in summer, which is associated with temperature distribution. Under the influence of a pressure gradient, air experiences acceleration directed from areas of high pressure to areas of low pressure, which leads to the movement of air masses. Moving air masses are also affected by the deflecting force of the Earth's rotation (Coriolis force), the friction force, which decreases with height, and, for curved trajectories, the centrifugal force. Turbulent mixing of air is of great importance (see Turbulence in the atmosphere).

A complex system of air currents (general atmospheric circulation) is associated with the planetary pressure distribution. In the meridional plane, on average, two or three meridional circulation cells can be traced. Near the equator, heated air rises and falls in the subtropics, forming a Hadley cell. The air of the reverse Ferrell cell also descends there. At high latitudes, a straight polar cell is often visible. Meridional circulation velocities are on the order of 1 m/s or less. Due to the Coriolis force, westerly winds are observed in most of the atmosphere with speeds in the middle troposphere of about 15 m/s. There are relatively stable wind systems. These include trade winds - winds blowing from high pressure zones in the subtropics to the equator with a noticeable eastern component (from east to west). Monsoons are fairly stable - air currents that have a clearly defined seasonal character: they blow from the ocean to the mainland in the summer and in the opposite direction in the winter. The Indian Ocean monsoons are especially regular. In mid-latitudes, the movement of air masses is mainly westerly (from west to east). This is a zone of atmospheric fronts on which large vortices arise - cyclones and anticyclones, covering many hundreds and even thousands of kilometers. Cyclones also occur in the tropics; here they are distinguished by their smaller sizes, but very high wind speeds, reaching hurricane force (33 m/s or more), the so-called tropical cyclones. In the Atlantic and eastern Pacific Oceans they are called hurricanes, and in the western Pacific Ocean they are called typhoons. In the upper troposphere and lower stratosphere, in the areas separating the direct Hadley meridional circulation cell and the reverse Ferrell cell, relatively narrow, hundreds of kilometers wide, jet streams with sharply defined boundaries are often observed, within which the wind reaches 100-150 and even 200 m/ With.

Climate and weather. The difference in the amount of solar radiation arriving at different latitudes to the earth's surface, which is varied in its physical properties, determines the diversity of the Earth's climates. From the equator to tropical latitudes, the air temperature at the earth's surface averages 25-30°C and varies little throughout the year. In the equatorial belt, there is usually a lot of precipitation, which creates conditions of excess moisture there. In tropical zones, precipitation decreases and in some areas becomes very low. Here are the vast deserts of the Earth.

In subtropical and middle latitudes, air temperature varies significantly throughout the year, and the difference between summer and winter temperatures is especially large in areas of the continents far from the oceans. Thus, in some areas of Eastern Siberia, the annual air temperature range reaches 65°C. Humidification conditions in these latitudes are very diverse, depend mainly on the regime of general atmospheric circulation and vary significantly from year to year.

In polar latitudes, the temperature remains low throughout the year, even if there is a noticeable seasonal variation. This contributes to the widespread distribution of ice cover on the oceans and land and permafrost, which occupy over 65% of its area in Russia, mainly in Siberia.

Over the past decades, changes in the global climate have become increasingly noticeable. Temperatures rise more at high latitudes than at low latitudes; more in winter than in summer; more at night than during the day. Over the 20th century, the average annual air temperature at the earth's surface in Russia increased by 1.5-2°C, and in some areas of Siberia an increase of several degrees was observed. This is associated with an increase in the greenhouse effect due to an increase in the concentration of trace gases.

The weather is determined by the conditions of atmospheric circulation and the geographical location of the area; it is most stable in the tropics and most variable in the middle and high latitudes. The weather changes most of all in zones of changing air masses caused by the passage of atmospheric fronts, cyclones and anticyclones carrying precipitation and increased wind. Data for weather forecasting are collected at ground-based weather stations, ships and aircraft, and from meteorological satellites. See also Meteorology.

Optical, acoustic and electrical phenomena in the atmosphere. When electromagnetic radiation propagates in the atmosphere, as a result of refraction, absorption and scattering of light by air and various particles (aerosol, ice crystals, water drops), various optical phenomena arise: rainbows, crowns, halo, mirage, etc. The scattering of light determines the apparent height of the vault of heaven and blue color of the sky. The visibility range of objects is determined by the conditions of light propagation in the atmosphere (see Atmospheric visibility). The transparency of the atmosphere at different wavelengths determines the communication range and the ability to detect objects with instruments, including the possibility of astronomical observations from the Earth’s surface. For studies of optical inhomogeneities of the stratosphere and mesosphere, the twilight phenomenon plays an important role. For example, photographing twilight from spacecraft makes it possible to detect aerosol layers. Features of the propagation of electromagnetic radiation in the atmosphere determine the accuracy of methods for remote sensing of its parameters. All these questions, as well as many others, are studied by atmospheric optics. Refraction and scattering of radio waves determine the possibilities of radio reception (see Propagation of radio waves).

The propagation of sound in the atmosphere depends on the spatial distribution of temperature and wind speed (see Atmospheric acoustics). It is of interest for atmospheric sensing by remote methods. Explosions of charges launched by rockets into the upper atmosphere provided rich information about wind systems and temperature variations in the stratosphere and mesosphere. In a stably stratified atmosphere, when the temperature decreases with height slower than the adiabatic gradient (9.8 K/km), so-called internal waves arise. These waves can propagate upward into the stratosphere and even into the mesosphere, where they attenuate, contributing to increased winds and turbulence.

The negative charge of the Earth and the resulting electric field, the atmosphere, together with the electrically charged ionosphere and magnetosphere, create a global electrical circuit. The formation of clouds and thunderstorm electricity plays an important role in this. The danger of lightning discharges has necessitated the development of lightning protection methods for buildings, structures, power lines and communications. This phenomenon poses a particular danger to aviation. Lightning discharges cause atmospheric radio interference, called atmospherics (see Whistling atmospherics). During a sharp increase in the electric field strength, luminous discharges are observed that appear on the tips and sharp corners of objects protruding above the earth's surface, on individual peaks in the mountains, etc. (Elma lights). The atmosphere always contains a greatly varying amount of light and heavy ions, depending on specific conditions, which determine the electrical conductivity of the atmosphere. The main ionizers of air near the earth's surface are radiation from radioactive substances contained in the earth's crust and atmosphere, as well as cosmic rays. See also Atmospheric electricity.

Human influence on the atmosphere. Over the past centuries, there has been an increase in the concentration of greenhouse gases in the atmosphere due to human economic activities. The percentage of carbon dioxide increased from 2.8-10 2 two hundred years ago to 3.8-10 2 in 2005, the methane content - from 0.7-10 1 approximately 300-400 years ago to 1.8-10 -4 at the beginning of the 21st century; about 20% of the increase in the greenhouse effect over the last century came from freons, which were practically absent in the atmosphere until the mid-20th century. These substances are recognized as stratospheric ozone depleters, and their production is prohibited by the 1987 Montreal Protocol. The increase in the concentration of carbon dioxide in the atmosphere is caused by the burning of ever-increasing amounts of coal, oil, gas and other types of carbon fuels, as well as the clearing of forests, as a result of which the absorption of carbon dioxide through photosynthesis decreases. The concentration of methane increases with an increase in oil and gas production (due to its losses), as well as with the expansion of rice crops and an increase in the number of cattle. All this contributes to climate warming.

To change the weather, methods have been developed to actively influence atmospheric processes. They are used to protect agricultural plants from hail by dispersing special reagents in thunderclouds. There are also methods for dispersing fog at airports, protecting plants from frost, influencing clouds to increase precipitation in desired areas, or for dispersing clouds during public events.

Study of the atmosphere. Information about physical processes in the atmosphere is obtained primarily from meteorological observations, which are carried out by a global network of permanently operating meteorological stations and posts located on all continents and on many islands. Daily observations provide information about air temperature and humidity, atmospheric pressure and precipitation, cloudiness, wind, etc. Observations of solar radiation and its transformations are carried out at actinometric stations. Of great importance for studying the atmosphere are networks of aerological stations, at which meteorological measurements are carried out up to an altitude of 30-35 km using radiosondes. At a number of stations, observations of atmospheric ozone, electrical phenomena in the atmosphere, and the chemical composition of the air are carried out.

Data from ground stations are supplemented by observations on the oceans, where “weather ships” operate, constantly located in certain areas of the World Ocean, as well as meteorological information received from research and other ships.

In recent decades, an increasing amount of information about the atmosphere has been obtained using meteorological satellites, which carry instruments for photographing clouds and measuring fluxes of ultraviolet, infrared and microwave radiation from the Sun. Satellites make it possible to obtain information about vertical profiles of temperature, cloudiness and its water supply, elements of the radiation balance of the atmosphere, ocean surface temperature, etc. Using measurements of the refraction of radio signals from a system of navigation satellites, it is possible to determine vertical profiles of density, pressure and temperature, as well as moisture content in the atmosphere . With the help of satellites, it has become possible to clarify the value of the solar constant and planetary albedo of the Earth, build maps of the radiation balance of the Earth-atmosphere system, measure the content and variability of small atmospheric pollutants, and solve many other problems of atmospheric physics and environmental monitoring.

Lit.: Budyko M.I. Climate in the past and future. L., 1980; Matveev L. T. Course of general meteorology. Atmospheric physics. 2nd ed. L., 1984; Budyko M.I., Ronov A.B., Yanshin A.L. History of the atmosphere. L., 1985; Khrgian A. Kh. Atmospheric Physics. M., 1986; Atmosphere: Directory. L., 1991; Khromov S.P., Petrosyants M.A. Meteorology and climatology. 5th ed. M., 2001.

G. S. Golitsyn, N. A. Zaitseva.

ATMOSPHERE
gaseous envelope surrounding a celestial body. Its characteristics depend on the size, mass, temperature, rotation speed and chemical composition of a given celestial body, and are also determined by the history of its formation from the moment of its inception. The Earth's atmosphere is made up of a mixture of gases called air. Its main components are nitrogen and oxygen in a ratio of approximately 4:1. A person is affected mainly by the state of the lower 15-25 km of the atmosphere, since it is in this lower layer that the bulk of the air is concentrated. The science that studies the atmosphere is called meteorology, although the subject of this science is also the weather and its effect on humans. The state of the upper layers of the atmosphere, located at altitudes from 60 to 300 and even 1000 km from the Earth's surface, also changes. Strong winds, storms develop here, and amazing electrical phenomena such as auroras occur. Many of the listed phenomena are associated with the flow of solar radiation, cosmic radiation, and the Earth's magnetic field. The high layers of the atmosphere are also a chemical laboratory, since there, under conditions close to vacuum, some atmospheric gases, under the influence of a powerful flow of solar energy, enter into chemical reactions. The science that studies these interrelated phenomena and processes is called high-atmospheric physics.
GENERAL CHARACTERISTICS OF THE EARTH'S ATMOSPHERE
Dimensions. Until sounding rockets and artificial satellites explored the outer layers of the atmosphere at distances several times greater than the radius of the Earth, it was believed that as we move away from the earth's surface, the atmosphere gradually becomes more rarefied and smoothly passes into interplanetary space. It has now been established that energy flows from the deep layers of the Sun penetrate into outer space far beyond the Earth’s orbit, right up to the outer limits of the Solar System. This so-called The solar wind flows around the Earth's magnetic field, forming an elongated "cavity" within which the Earth's atmosphere is concentrated. The Earth's magnetic field is noticeably narrowed on the day side facing the Sun and forms a long tongue, probably extending beyond the Moon's orbit, on the opposite, night side. The boundary of the Earth's magnetic field is called the magnetopause. On the daytime side, this boundary runs at a distance of about seven Earth radii from the surface, but during periods of increased solar activity it turns out to be even closer to the Earth’s surface. The magnetopause is also the boundary of the Earth's atmosphere, the outer shell of which is also called the magnetosphere, since charged particles (ions) are concentrated in it, the movement of which is determined by the Earth's magnetic field. The total weight of atmospheric gases is approximately 4.5 * 1015 tons. Thus, the “weight” of the atmosphere per unit area, or atmospheric pressure, is approximately 11 tons/m2 at sea level.
Meaning for life. From the above it follows that the Earth is separated from interplanetary space by a powerful protective layer. Outer space is permeated with powerful ultraviolet and x-ray radiation from the Sun and even harder cosmic radiation, and these types of radiation are destructive to all living things. At the outer edge of the atmosphere, the radiation intensity is lethal, but much of it is retained by the atmosphere far from the Earth's surface. The absorption of this radiation explains many of the properties of the high layers of the atmosphere and especially the electrical phenomena occurring there. The lowest, ground-level layer of the atmosphere is especially important for humans, who live at the point of contact between the solid, liquid and gaseous shells of the Earth. The upper shell of the “solid” Earth is called the lithosphere. About 72% of the Earth's surface is covered by ocean waters, which make up most of the hydrosphere. The atmosphere borders both the lithosphere and the hydrosphere. Man lives at the bottom of the ocean of air and near or above the level of the ocean of water. The interaction of these oceans is one of the important factors determining the state of the atmosphere.
Compound. The lower layers of the atmosphere consist of a mixture of gases (see table). In addition to those listed in the table, other gases are present in the form of small impurities in the air: ozone, methane, substances such as carbon monoxide (CO), nitrogen and sulfur oxides, ammonia.

COMPOSITION OF THE ATMOSPHERE

Troposphere

Its upper limit is at an altitude of 8-10 km in polar, 10-12 km in temperate and 16-18 km in tropical latitudes; lower in winter than in summer. The lower, main layer of the atmosphere contains more than 80% of the total mass of atmospheric air and about 90% of all water vapor present in the atmosphere. Turbulence and convection are highly developed in the troposphere, clouds arise, and cyclones and anticyclones develop. Temperature decreases with increasing altitude with an average vertical gradient of 0.65°/100 m

Tropopause

The transition layer from the troposphere to the stratosphere, a layer of the atmosphere in which the decrease in temperature with height stops.

Stratosphere

A layer of the atmosphere located at an altitude of 11 to 50 km. Characterized by a slight change in temperature in the 11-25 km layer (lower layer of the stratosphere) and an increase in temperature in the 25-40 km layer from −56.5 to 0.8 ° C (upper layer of the stratosphere or inversion region). Having reached a value of about 273 K (almost 0 °C) at an altitude of about 40 km, the temperature remains constant up to an altitude of about 55 km. This region of constant temperature is called the stratopause and is the boundary between the stratosphere and mesosphere.

Stratopause

The boundary layer of the atmosphere between the stratosphere and mesosphere. In the vertical temperature distribution there is a maximum (about 0 °C).

Mesosphere

The mesosphere begins at an altitude of 50 km and extends to 80-90 km. Temperature decreases with height with an average vertical gradient of (0.25-0.3)°/100 m. The main energy process is radiant heat transfer. Complex photochemical processes involving free radicals, vibrationally excited molecules, etc. cause atmospheric luminescence.

Mesopause

Transitional layer between the mesosphere and thermosphere. There is a minimum in the vertical temperature distribution (about -90 °C).

Karman Line

The height above sea level, which is conventionally accepted as the boundary between the Earth's atmosphere and space. The Karman line is located at an altitude of 100 km above sea level.

Boundary of the Earth's atmosphere

Thermosphere

The upper limit is about 800 km. The temperature rises to altitudes of 200-300 km, where it reaches values ​​of the order of 1500 K, after which it remains almost constant to high altitudes. Under the influence of ultraviolet and x-ray solar radiation and cosmic radiation, ionization of the air (“auroras”) occurs - the main regions of the ionosphere lie inside the thermosphere. At altitudes above 300 km, atomic oxygen predominates. The upper limit of the thermosphere is largely determined by the current activity of the Sun. During periods of low activity, a noticeable decrease in the size of this layer occurs.

Thermopause

The region of the atmosphere adjacent to the thermosphere. In this region, the absorption of solar radiation is negligible and the temperature does not actually change with altitude.

Exosphere (scattering sphere)

Atmospheric layers up to an altitude of 120 km

The exosphere is a dispersion zone, the outer part of the thermosphere, located above 700 km. The gas in the exosphere is very rarefied, and from here its particles leak into interplanetary space (dissipation).

Up to an altitude of 100 km, the atmosphere is a homogeneous, well-mixed mixture of gases. In higher layers, the distribution of gases by height depends on their molecular weights; the concentration of heavier gases decreases faster with distance from the Earth's surface. Due to the decrease in gas density, the temperature drops from 0 °C in the stratosphere to −110 °C in the mesosphere. However, the kinetic energy of individual particles at altitudes of 200-250 km corresponds to a temperature of ~150 °C. Above 200 km, significant fluctuations in temperature and gas density in time and space are observed.

At an altitude of about 2000-3500 km, the exosphere gradually turns into the so-called near-space vacuum, which is filled with highly rarefied particles of interplanetary gas, mainly hydrogen atoms. But this gas represents only part of the interplanetary matter. The other part consists of dust particles of cometary and meteoric origin. In addition to extremely rarefied dust particles, electromagnetic and corpuscular radiation of solar and galactic origin penetrates into this space.

The troposphere accounts for about 80% of the mass of the atmosphere, the stratosphere - about 20%; the mass of the mesosphere is no more than 0.3%, the thermosphere is less than 0.05% of the total mass of the atmosphere. Based on the electrical properties in the atmosphere, the neutronosphere and ionosphere are distinguished. It is currently believed that the atmosphere extends to an altitude of 2000-3000 km.

Depending on the composition of the gas in the atmosphere, homosphere and heterosphere are distinguished. The heterosphere is an area where gravity affects the separation of gases, since their mixing at such a height is negligible. This implies a variable composition of the heterosphere. Below it lies a well-mixed, homogeneous part of the atmosphere called the homosphere. The boundary between these layers is called the turbopause; it lies at an altitude of about 120 km.

The Earth's primary atmosphere consisted mainly of water vapor, hydrogen and ammonia. Under the influence of ultraviolet radiation from the Sun, water vapor decomposed into hydrogen and oxygen. Hydrogen largely escaped into outer space, oxygen reacted with ammonia and nitrogen and water were formed. At the beginning of geological history, the Earth, thanks to the magnetosphere, which isolated it from the solar wind, created its own secondary carbon dioxide atmosphere. Carbon dioxide came from the depths during intense volcanic eruptions. With the appearance of green plants at the end of the Paleozoic, oxygen began to enter the atmosphere as a result of the decomposition of carbon dioxide during photosynthesis, and the composition of the atmosphere took on its modern form. The modern atmosphere is largely a product of the living matter of the biosphere. Complete renewal of the planet's oxygen by living matter occurs in 5200-5800 years. Its entire mass is absorbed by living organisms in approximately 2 thousand years, all carbon dioxide - in 300-395 years.

Composition of the primary and modern atmosphere of the Earth

Also present in the primary atmosphere were methane, ammonia, hydrogen, etc. Free oxygen appeared in the atmosphere 1.8-2 billion years ago.

Origin and evolution of the atmosphere (according to V.A. Vronsky and G.V. Voitkovich)

Even during the initial radioactive heating of the young Earth, volatile substances were released to the surface, forming the primary ocean and the primary atmosphere. It can be assumed that the primary atmosphere of our planet was close in composition to the composition of meteorite and volcanic gases. To some extent, the primary atmosphere (CO 2 content was 98%, argon - 0.19%, nitrogen - 1.5%) was similar to the atmosphere of Venus, the planet that is closest in size to our planet.

The Earth's primary atmosphere was of a reducing nature and was practically devoid of free oxygen. Only a small part of it arose in the upper layers of the atmosphere as a result of the dissociation of carbon dioxide and water molecules. Currently, there is a general consensus that at a certain stage in the development of the Earth, its carbon dioxide atmosphere turned into a nitrogen-oxygen atmosphere. However, the question remains unclear regarding the time and nature of this transition - in what era of the history of the biosphere the turning point occurred, whether it was rapid or gradual.

Currently, data have been obtained on the presence of free oxygen in the Precambrian. The presence of highly oxidized iron compounds in the red bands of Precambrian iron ores indicates the presence of free oxygen. The increase in its content throughout the history of the biosphere was determined by constructing appropriate models of varying degrees of reliability (A.P. Vinogradov, G. Holland, J. Walker, M. Shidlovsky, etc.). According to A.P. Vinogradov, the composition of the atmosphere changed continuously and was regulated both by the processes of degassing of the mantle and by physicochemical factors that took place on the Earth’s surface, including cooling and, accordingly, a decrease in ambient temperature. The chemical evolution of the atmosphere and hydrosphere in the past was closely linked in the balance of their substances.

The abundance of buried organic carbon is taken as the basis for calculations of the past composition of the atmosphere, as having passed the photosynthetic stage in the cycle associated with the release of oxygen. With decreasing degassing of the mantle during geological history, the total mass of sedimentary rocks gradually approached modern ones. At the same time, 4/5 of the carbon was buried in carbonate rocks, and 1/5 was accounted for by organic carbon of sedimentary strata. Based on these premises, the German geochemist M. Shidlovsky calculated the increase in the content of free oxygen during the geological history of the Earth. It was found that approximately 39% of all oxygen released during photosynthesis was bound in Fe 2 O 3, 56% was concentrated in SO 4 2 sulfates, and 5% continuously remained in a free state in the Earth’s atmosphere.

In the Early Precambrian, almost all of the released oxygen was quickly absorbed by the earth's crust during oxidation, as well as by volcanic sulfur gases of the primary atmosphere. It is likely that the processes of formation of banded ferruginous quartzites (jaspelites) in the Early and Middle Precambrian led to the absorption of a significant part of the free oxygen from photosynthesis of the ancient biosphere. Ferrous iron in Precambrian seas was the main oxygen absorber when photosynthetic marine organisms supplied free molecular oxygen directly to the aquatic environment. After the Precambrian oceans were cleared of dissolved iron, free oxygen began to accumulate in the hydrosphere and then in the atmosphere.

A new stage in the history of the biosphere was characterized by the fact that in the atmosphere 2000-1800 million years ago there was an increase in the amount of free oxygen. Therefore, the oxidation of iron moved to the surface of ancient continents in the area of ​​the weathering crust, which led to the formation of powerful ancient red-colored strata. The supply of ferrous iron to the ocean has decreased and, accordingly, the absorption of free oxygen by the marine environment has decreased. An increasing amount of free oxygen began to enter the atmosphere, where its constant content was established. In the overall balance of atmospheric oxygen, the role of biochemical processes of living matter in the biosphere has increased. The modern stage in the history of oxygen in the Earth's atmosphere began with the appearance of vegetation on the continents. This led to a significant increase in its content compared to the ancient atmosphere of our planet.

Literature

1. Vronsky V.A. Fundamentals of paleogeography / V.A. Vronsky, G.V. Voitkevich. - Rostov n/d: publishing house "Phoenix", 1997. - 576 p.
2. Zubaschenko E.M. Regional physical geography. Climates of the Earth: educational and methodological manual. Part 1. / E.M. Zubaschenko, V.I. Shmykov, A.Ya. Nemykin, N.V. Polyakova. – Voronezh: VSPU, 2007. – 183 p.